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PEEK Rods Thermal Performance Data: Continuous Service Temp, HDT, CLTE & Thermal Conductivity

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heat-resistance PEEK rods

Key Takeaways

  • All PEEK rods operate continuously at 260°C, but HDT varies by grade.

  • CF30 and GF30 raise HDT to 315°C under load.

  • CF30 reduces radial expansion by vs. unfilled PEEK.

  • CF30 triples thermal conductivity (0.95 W/m·K) for heat dissipation.

  • Always use radial CLTE for bushing and seal design.



PEEK rods deliver continuous service at 260°C and share the same chemical resistance across all grades, but their thermal behavior under load varies significantly. When selecting a grade for high‑temperature applications, engineers must evaluate Heat Deflection Temperature (HDT), Coefficient of Linear Thermal Expansion (CLTE), and thermal conductivity—not just the maximum operating temperature.

Four PEEK rod grades are commonly specified for thermal performance: Unfilled (Virgin), 30% Glass Fiber (GF30), 30% Carbon Fiber (CF30), and Bearing Grade. Each grade modifies how the material conducts heat, expands under temperature, and retains rigidity under mechanical load.

This guide focuses on the thermal performance of extruded PEEK rods, providing ISO‑tested data to support precision engineering in semiconductor, aerospace, and medical applications.

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The Thermal performance of Different grades PEEK rods

What is HDT of different PEEK rods?

What is Coefficient of Linear Thermal Expansion of different PEEK rods?

The Thermal conductivity of different PEEK rods

The Thermal performance of Different grades PEEK rods

All grades of PEEK rods possess excellent high-temperature resistance. Their glass transition temperatures(Tg) are all at 143°C, and they can operate for a long time in an environment of 260°C. The short-term operating temperature can reach 300°C. However, apart from the working temperature, there are significant differences in their heat distortion temperature (HDT), thermal conductivity, and linear expansion coefficient, which are also worthy of our attention.

What is HDT of different PEEK rods?

PEEK's Heat Deflection Temperature (HDT) refers to the temperature at which PEEK material, under a specified bending load, reaches the specified deflection due to heat. It is not the melting point of the material but the practical upper limit for PEEK to maintain its rigidity under the combined effect of "load + heating". 

  • Unfilled PEEK rods HDT(ISO 75,load 1.8Mpa) is 152°C

  • PEEK GF30 rods HDT(ISO 75,load 1.8Mpa) is 315°C

  • PEEK CF30 rods HDT(ISO 75,load 1.8Mpa) is 315°C

  • Bearing grade PEEK rods HDT(ISO 75,load 1.8Mpa) is 315°C

As we can see,the glass fiber and carbon fiber can Significant improve the HDT of PEEK rods.

If you need higher HDT,reinforced grade PEEK rods is more suitable for you

50mm diameterial PEEK rods

What is Coefficient of Linear Thermal Expansion of different PEEK rods?

For precision components machined from PEEK rods, the Coefficient of Linear Thermal Expansion (CLTE) serves as a critical input parameter for dimensional stability design under thermal cycling, directly governing part fit, sealing integrity, and service life in applications subject to elevated temperatures, rapid thermal transients, or strict tolerance control—such as semiconductor wafer carriers, aerospace hydraulic manifolds, and implantable surgical instrumentation. 

Unlike the melt flow orientation characteristics of injection-molded parts, the molecular chains and reinforcing fibers of PEEK extruded rods align in a highly ordered manner along the extrusion axis. This structural anisotropy results in significant differences in the CLTE of the rods along the axial direction (parallel to the extrusion direction) and the radial direction (perpendicular to the extrusion direction).

We can use the data of PEEK injection sample plate as a reference, but it is necessary to clearly note the numerical differences caused by the 2 processes.

PEEK Rod Coefficient of Linear Thermal Expansion (CLTE) Reference Table(Tested per ISO 11359)
Grade
Direction
23–143°C (Below Tg)
143–260°C (Above Tg)
Unfilled PEEK
Axial
45 ppm/K
120 ppm/K

Radial
55 ppm/K
130 ppm/K
PEEK GF30
Axial
18 ppm/K
18 ppm/K

Radial
35 ppm/K
35 ppm/K
PEEK CF30
Axial
5 ppm/K
6 ppm/K

Radial
25 ppm/K
27 ppm/K
• For tight‑tolerance bushings and seals, use the Radial CLTE.
• CF30 offers the best dimensional stability, with radial expansion still 5× lower than unfilled PEEK.
• Post‑machining annealing is recommended for parts operating near 260°C.

The Thermal conductivity of different PEEK rods

PEEK is a semi-crystalline aromatic thermoplastic polymer. Its regular molecular chains and stable crystalline regions provide thermal stability that far exceeds that of standard engineering plastics—maintaining continuous service capability at 260°C despite a relatively low Tg of 143°C. However, its molecular structure inhibits phonon and free-electron transport, resulting in a low thermal conductivity of approximately 0.25 W/(m·K)—roughly 1/60 that of stainless steel and just 1/800 that of aluminum.

PEEK rods resist softening and mechanical failure under heat while simultaneously acting as effective thermal barriers. 

low Thermal conductivity PEEK rods

This unique combination is precisely what makes them irreplaceable for high-temperature fixtures, semiconductor process components, and electrically insulating structural parts.

  • Unfilled PEEK rods Thermal conductivity is 0.29W/(m·K)

  • PEEK GF30 rods Thermal conductivity is 0.3W/(m·K)

  • PEEK CF30 rods Thermal conductivity is 0.95W/(m·K)

Note:These data is under standard ISO 22007-4,the test condition is 23°C

Category
Specific Material
Thermal Conductivity W/(m·K)
Multiple of Virgin PEEK
Test Standard
Metals (High Conductivity)
Copper (Cu)
385–401
~1400×
ASTM E1225
Aluminum (Al 6061)
167–205
~700×
ASTM E1225
Steel (Carbon)
45–55
~180×
ASTM E1225
Stainless Steel 304
14.6–16.2
~55×
ASTM E1225
Titanium (Ti-6Al-4V)
6.7–7.2
~25×
ASTM E1225
Application Insight:
• Unfilled and GF30 PEEK act as thermal barriers, ideal for electrically insulating fixtures.
• CF30 dissipates heat 3× faster than unfilled PEEK, making it suitable for dry‑running bearings and heat‑cycling components.

PEEK Rod Thermal Performance - FAQ

Q:What is the maximum continuous operating temperature of PEEK rods?
A:All PEEK rod grades (Unfilled, GF30, CF30, Bearing Grade) support continuous service at 260°C (500°F) and short-term exposure up to 300°C. The key difference between grades is not the operating temperature but the Heat Deflection Temperature (HDT) under load.
Q:Which PEEK rod grade has the highest Heat Deflection Temperature (HDT)?
A:Reinforced grades offer significantly higher HDT than unfilled PEEK. Both PEEK CF30 and PEEK GF30 reach 315°C @ 1.8 MPa (ISO 75), compared to just 152°C for unfilled PEEK rods. For applications requiring rigidity under sustained high-temperature loads, choose a reinforced grade.
Q:Is PEEK a good thermal conductor?
A:Standard PEEK is a thermal insulator at approximately 0.29 W/(m·K), roughly 1/60 that of stainless steel and 1/800 that of aluminum. However, PEEK CF30 increases thermal conductivity to 0.95 W/(m·K)—about 3× higher—making it suitable for dry-running bearings and heat-cycling components. Unfilled and GF30 grades remain excellent thermal barriers for electrically insulating fixtures.
Q:How does extrusion affect PEEK rod thermal expansion (CLTE)?
A:Extruded PEEK rods exhibit anisotropy due to molecular alignment during processing. The radial CLTE is significantly higher than the axial CLTE. For example, unfilled PEEK has an axial CLTE of 45 ppm/K but a radial CLTE of approximately 55 ppm/K below Tg. For precision bushings, seals, or any tight-tolerance parts, always use the radial CLTE value for design calculations.
Q:What is the difference between axial and radial CLTE in PEEK rods?
A:Axial CLTE measures expansion along the length of the rod (parallel to extrusion direction), while radial CLTE measures expansion across the diameter (perpendicular to extrusion direction). Carbon fiber reinforcement (CF30) minimizes both: axial CLTE drops to 5 ppm/K and radial to approximately 25 ppm/K below Tg—making CF30 the best choice for dimensionally stable, high-temperature components.
Q:Which PEEK rod grade should I choose for high-temperature sealing applications?
A:For high-temperature seals and bushings, PEEK CF30 is the recommended choice. It combines a high HDT of 315°C, the lowest radial CLTE among reinforced grades, and 3× higher thermal conductivity than unfilled PEEK. If chemical resistance is the primary concern and loads are light, unfilled PEEK at 260°C continuous service remains a cost-effective option.
Q:Are the thermal data values for extruded PEEK rods the same as injection-molded specimens?
A:No. Injection-molded specimens typically show higher HDT values (up to 340°C for reinforced grades) due to different molecular orientation and fillers distribution. Extruded PEEK rods exhibit slightly lower HDT ( 315°C) and significant anisotropy in CLTE. The values presented in this guide are typical reference data per ISO standards; lot-specific Certified Analysis reports are available upon request from the PRES technical team.

Rio Liang | High-Performance Plastics Expert
 
Email: rioplastic@foxmail.com   TEL/Whatsapp/Wechat: 008613421811533
 
20+ Years specializing in PEEK, PPSU, PES, PPS & PEI materil modification. Expert in resolving material properties and injection molding solutions. Open to technical discussions.

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