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PEEK material temperature range spans from -60°C (-76°F) continuous service up to 260°C (500°F) continuous operating temperature, with short-term peak capability at 300°C (572°F). At the cold end, Victrex Pipes PEEK tubing is proven with no break in crush test at -60°C and retains impact resistance at -70°C (-94°F). At the hot end, Victrex 450G and equivalent grades carry a UL RTI of 260°C for electrical applications. This gives PEEK a continuous-service spread of over 320°C — the widest of any melt-processable thermoplastic.
| Parameter | Value | What It Means for Design |
|---|---|---|
| Glass Transition (Tg) | 143°C (289°F) | Above this, amorphous regions soften. Below it, PEEK is rigid and dimensionally stable — even at -60°C. |
| Melting Point (Tm) | 343°C (649°F) | The absolute upper thermal limit. PEEK loses all load-bearing ability above Tm. |
| Continuous Service Temp | 260°C (500°F) | Maximum temperature for indefinite use under load (Victrex 450G, unfilled). |
| Peak / Short-Term Temp | 300°C (572°F) | Maximum temperature for brief excursions (minutes to hours) without permanent deformation. |
PEEK is engineered for continuous service down to -60°C (-76°F). Victrex's official PEEK tubing qualification provides the most rigorous published low-temperature proof:
Crush test at -60°C: No break — structural integrity fully retained.
Impact resistance at -70°C: Reliable performance — no loss of impact resistance demonstrated.
Certification: Passed DNV GL RP F119 for offshore and subsea service.
These results apply to extruded, uninforced PEEK tubing. For stock shapes (sheet, rod, molded parts), -60°C is the conservative, defensible lower design limit across the industry.
PEEK's energy absorption capability drops as temperature falls. Research (García-González et al., Composite Structures 2015) confirms:
Unfilled PEEK suffers a sudden loss of impact energy absorption below its transition zone.
CF30 short-carbon-fiber PEEK exhibits brittle behavior across the entire -75°C to +25°C range.
| Load Type | -60°C Behavior | Design Guidance |
|---|---|---|
| Static / Compression / Crush | Proven safe (Victrex crush test) | Safe at -60°C |
| Impact-dominated | Unfilled PEEK safe; CF30 needs validation | Use unfilled PEEK only below -40°C impact |
| Dynamic fatigue | Proven -60°C to -70°C (Victrex Pipes) | Safe for unfilled PEEK |
PEEK's 260°C continuous rating depends on three variables:
Load: At zero mechanical load, PEEK can endure 260°C+ indefinitely. Under sustained stress, the ceiling is ~250-260°C. At 200°C, PEEK retains over 60% of room-temperature tensile strength.
Crystallinity: Annealed/slow-cooled PEEK (~35-45% crystallinity) resists creep better than fast-cooled parts.
Media: In hot water/steam, properties retained up to 260°C. In aggressive chemicals, the limit may drop to 200-230°C.
| RTI Category | Rating |
|---|---|
| Electrical | 260°C |
| Mechanical with Impact | 240°C |
| Mechanical without Impact | 180°C |
PEEK can serve as an electrical insulator at 260°C for the product's lifetime, but structural parts under impact should be derated to 240°C.
| Material | Lower Limit | Upper Limit (Continuous) | Spread |
|---|---|---|---|
| PEEK | -60°C (-76°F) | 260°C (500°F) | 320°C+ |
| PI (Polyimide) | -269°C | 260-300°C | 530°C+ |
| PAI (Torlon) | -190°C | 260°C | 450°C |
| PEI (Ultem) | -40°C | 170°C | 210°C |
| PPS | -40°C | 220°C | 260°C |
| PPSU | -50°C | 180°C | 230°C |
| PTFE | -200°C+ | 260°C | 460°C+ |
| POM (Acetal) | -40°C | 100°C | 140°C |
PEEK is the only melt-processable thermoplastic combining a sub-zero cold limit with a 260°C continuous hot limit and full chemical resistance.
| Grade | Lower Limit | Upper Limit (Continuous) | Notes |
|---|---|---|---|
| Unfilled PEEK | -60°C (proven -70°C impact) | 260°C | Best all-around; optimal low-temp impact. |
| GF30 PEEK | -50°C (impact); -60°C (static) | 260°C+ | Glass fiber adds rigidity; slightly reduces low-temp impact. |
| CF30 PEEK | -40°C (avoid impact); -60°C (compression) | 260°C+ | Carbon fiber improves wear; causes brittle behavior below -40°C under impact. |
| ESD PEEK | -50°C (static); -40°C (impact) | 260°C | Carbon filler increases low-temp brittleness similar to CF30. |
Zone A: -40°C to +260°C — Full-performance window. All PEEK grades, all load types. Aerospace exterior, automotive under-hood, electrical connectors, pump components.
Zone B: -60°C to +260°C — Proven PEEK service. Unfilled PEEK: all load types safe. GF30/CF30: compression/static safe; avoid impact-critical. Subsea connectors, offshore tubing, Arctic oil & gas.
Zone C: Above 260°C to 300°C — Short-term / peak only. Brief excursions only. Not for continuous service. Sterilization cycles, flash overheating events.
Myth 1: "PEEK works from -196°C to +260°C continuously."
False. While PEEK retains structural integrity at -196°C for brief periods, continuous cryogenic service with impact loads requires specialized grades. The defensible continuous lower limit is -60°C.
Myth 2: "All PEEK grades handle the same temperature range."
False. Unfilled PEEK is proven at -60°C crush / -70°C impact. CF30 exhibits brittle behavior from -75°C upward. Grade selection is critical for cold-end applications.
Myth 3: "PEEK can run at 300°C continuously."
False. 300°C is the short-term peak limit. Continuous service is 260°C maximum (or 250°C under sustained mechanical load).
| Temperature | Unfilled PEEK | GF30 PEEK | CF30 PEEK |
|---|---|---|---|
| -70°C (-94°F) | Proven impact (extruded tubing) | Static only | Brittle — not recommended |
| -60°C (-76°F) | Proven crush — no break | Compression OK | Compression OK; avoid impact |
| -40°C (-40°F) | Full performance | Full performance | Avoid impact-critical |
| +260°C (500°F) | Continuous max | Continuous max | Continuous max |
| +300°C (572°F) | Short-term peak only | Short-term peak only | Short-term peak only |
PEEK's proven continuous service range is from -60°C (-76°F) to 260°C (500°F), with short-term peak capability at 300°C (572°F). Victrex Pipes tubing is further proven at -70°C for impact resistance. This gives PEEK a usable spread of over 320°C.
Yes. PEEK is proven at -60°C with no break in crush test (Victrex Pipes qualification). For most engineering applications, -60°C is the defensible continuous-service lower limit. Impact-critical parts should use unfilled PEEK and avoid CF30 below -40°C.
260°C (500°F) continuous. Victrex 450G and equivalent unfilled grades carry a UL RTI of 260°C for electrical applications. Under sustained mechanical load, the practical continuous limit is approximately 250-260°C.
Yes, PEEK undergoes a ductile-to-brittle transition at low temperature. Unfilled PEEK loses impact energy absorption below its transition zone, and CF30 exhibits brittle behavior across -75°C to +25°C. For cold-climate impact applications, use unfilled PEEK.
Fillers do not significantly raise PEEK's upper limit (still ~260°C continuous), but they shift the lower limit. GF30 is safe to -50°C for impact, -60°C for static. CF30 should not be used for impact-critical parts below -40°C due to brittle behavior. Unfilled PEEK has the best low-temperature performance.
PEEK retains structural integrity at -196°C (liquid nitrogen) for brief periods, but energy absorption drops drastically and CF30 becomes fully brittle. Continuous cryogenic service requires specialized low-temperature grades and static-load validation.
ItemPPSPPSUChemical StructureBenzene ring + thioether bond -[C6H4-S]-nBiphenyl + sulfone group + ether bondCrystallinitySemi-crystalline (crystallinity 35–50%)AmorphousAppearanceOpaque (off-white/gray/black)Amber, translucentInherent Flame RetardancyUL94 V-0UL94 V-0Water AbsorptionExtremely low ~0.0
Ultra-high flow PEEK is more suitable for micro injection molding machines and high-precision products. PEEK with good fluidity requires less injection pressure and can better fill complex-shaped cavities.
DING Haoliang, TANG Wei, WEI Sai, LI Fan, ZHAO Yunfeng. Development of Bearing Bracket Made From Polyether Ketone by Shot Glass Fiber Reinforced. Aerospace Materials & Technology, 2018, 48(5): 73-77.
The injection parameters of PEEK material need to be adjusted at different levels. Before injection, the material needs to be dried at 150-160°C for 4 hours. The unfilled PEEK material has higher fluidity than the fiber-filled PEEK material, and a medium-high flow speed of 30-90mm/s can be adopted.